Effect of the Atmospheric Plasma Treatment Parameters on the Surface and Mechanical Properties of Carbon Fabric

The use of Atmospheric Pressure Plasma Jet (APPJ) technology for surface treatment of carbon fabrics is investigated to estimate the increase in the fracture toughness of carbon-fiber composite materials. Nitrogen and a nitrogen–hydrogen gas mixture were used to size the carbon fabrics by preliminarily optimizing the process parameters. The effects of the APPJ on the carbon fabrics were investigated by using optical and chemical characterizations. Optical Emission Spectroscopy, Fourier Transform Infrared-Attenuated Total Reflection, X-ray Photoelectron Spectroscopy and micro-Raman spectroscopy were adopted to assess the effectiveness of ablation and etching effects of the treatment, in terms of grafting of new functional groups and active sites. The treated samples showed an increase in chemical groups grafted onto the surfaces, and a change in carbon structure was influential in the case of chemical interaction with epoxy groups of the epoxy resin adopted. Flexural test, Double Cantilever Beam and End-Notched Flexure tests were then carried out to characterize the composite and evaluate the fracture toughness in Mode I and Mode II, respectively. N2/H2 specimens showed significant increases in GIC and GIIC, compared to the untreated specimens, and slight increases in Pmax at the first crack propagation.