Production of Graphene Stably Dispersible in Ethanol by Microwave Reaction

Graphene is a 2D carbon material with peculiar features such as high electrical conductivity, high thermal conductivity, mechanical stability, and a high ratio between surface and thickness. Applications are continuously growing, and the possibility of dispersing graphene in low-boiling green solvents could reduce its global environmental impact. Pristine graphene can be dispersed in high concentration only in polar aprotic solvents that usually have high boiling points and high toxicity. For this reason, the oxidized form of graphene is always used, as it is easier to disperse and to subsequently reduce to reduced graphene oxide. However, compared to pristine graphene, reduced graphene oxide has more defects and has inferior properties respect to graphene. In this work, the polymerization of (diethyl maleate derivate) on graphene obtained by sonication was performed in a microwave reactor. The obtained material has good stability in ethanol even after a long period of time, therefore, it can be used to deposit graphene by mass production of inks or by casting and easy removal of the solvent. The thermal annealing by heating at 300–400 ◦C in inert atmosphere allows the removal of the polymer to obtain pristine graphene with a low number of defects.