Relative contribution of chemico-osmosis and electro-osmosis to the experimental determination of the reflection coefficient in semipermeable clay soils

The containment performance of bentonite-based barriers is known to be influenced by the semipermeable membrane behaviour of the bentonite, which arises from the electrical interactions between the clay particles and the ionic species dissolved in the pore solution. Most of the experimental research conducted to date has provided evidence of the clay membrane behaviour, the extent of which is typically quantified through the reflection coefficient, , when the permeant (electrolyte) solution contains a monovalent or divalent salt. Under such conditions, the osmotic counter-flow of solution is controlled to a great extent by the solute exclusion, which is also referred to as the chemico-osmotic effect. However, theoretical simulations of coupled solute transport and solvent flow suggest that, when two or more cations with different diffusivities are contained in the permeant solution, the electro-osmotic effect, which stems from the condition of null electric current density, can be comparable to or even greater than the chemico-osmotic effect. The relative importance of the aforementioned contributions to multi-electrolyte systems is examined herein through the interpretation of laboratory test results from the literature pertaining to a bentonite-amended clay soil permeated with aqueous mixtures of potassium chloride (KCl) and hydrochloric acid (HCl).