The static dielectric constant of nonpolar liquids is described by analyzing the pair distribution function and the dipole-dipole interaction into a finite set of Fourier components. In a mean field approximation the theory leads to a final formula that does not contain any adjustable parameter, and proves to work better than the Clausius-Mossotti equation. The theory explains in a satisfactory way the temperature and pressure dependence of the dielectric constant of nonpolar liquids, as well as the temperature variation of the refractive index of many organic polar liquids. © 1976.

A theory of electric polarisation in liquids. I. Nonpolar liquids / Omini, M.. - In: PHYSICA. A. - ISSN 0378-4371. - 83:3(1976), pp. 431-453. [10.1016/0378-4371(75)90013-8]

A theory of electric polarisation in liquids. I. Nonpolar liquids

Omini M.
1976

Abstract

The static dielectric constant of nonpolar liquids is described by analyzing the pair distribution function and the dipole-dipole interaction into a finite set of Fourier components. In a mean field approximation the theory leads to a final formula that does not contain any adjustable parameter, and proves to work better than the Clausius-Mossotti equation. The theory explains in a satisfactory way the temperature and pressure dependence of the dielectric constant of nonpolar liquids, as well as the temperature variation of the refractive index of many organic polar liquids. © 1976.
1976
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11583/2934613