Archivio Istituzionale della RicercaAbstract: This paper describes the preparation, broad characterization and study of activity in hydrogenation and hydroformylation reactions of an easily produced 0.18% Rh/Al2O3. Analytical studies on fresh and recycled samples shed light on the smart properties of such catalyst. Results showed high activity as well as fine/excellent chemoselectivity or regioselectivity, characteristics that may suggest a wide range of applicability. Graphic Abstract: The low metal content catalyst 0.18% Rh/Al2O3 was very active in both hydrogenation and hydroformylation reactions so providing intermediates for valuable APIs, as Nabumetone and Eletriptan, and a fragrance with a fresh, green-floral smell, that recalls scent of lily of the valley.[Figure not available: see fulltext.]
A Low Rhodium Content Smart Catalyst for Hydrogenation and Hydroformylation Reactions / Paganelli, S.; Tassini, R.; Rathod, V. D.; Onida, B.; Fiorilli, S.; Piccolo, O.. - In: CATALYSIS LETTERS. - ISSN 1011-372X. - ELETTRONICO. - 151:(2021), pp. 1508-1521. [10.1007/s10562-020-03407-5]
A Low Rhodium Content Smart Catalyst for Hydrogenation and Hydroformylation Reactions
Onida B.;Fiorilli S.;
2021
Abstract
Abstract: This paper describes the preparation, broad characterization and study of activity in hydrogenation and hydroformylation reactions of an easily produced 0.18% Rh/Al2O3. Analytical studies on fresh and recycled samples shed light on the smart properties of such catalyst. Results showed high activity as well as fine/excellent chemoselectivity or regioselectivity, characteristics that may suggest a wide range of applicability. Graphic Abstract: The low metal content catalyst 0.18% Rh/Al2O3 was very active in both hydrogenation and hydroformylation reactions so providing intermediates for valuable APIs, as Nabumetone and Eletriptan, and a fragrance with a fresh, green-floral smell, that recalls scent of lily of the valley.[Figure not available: see fulltext.]
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https://hdl.handle.net/11583/2851570