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EnglishAbstract: This paper describes the preparation, broad characterization and study of activity in hydrogenation and hydroformylation reactions of an easily produced 0.18% Rh/Al2O3. Analytical studies on fresh and recycled samples shed light on the smart properties of such catalyst. Results showed high activity as well as fine/excellent chemoselectivity or regioselectivity, characteristics that may suggest a wide range of applicability. Graphic Abstract: The low metal content catalyst 0.18% Rh/Al2O3 was very active in both hydrogenation and hydroformylation reactions so providing intermediates for valuable APIs, as Nabumetone and Eletriptan, and a fragrance with a fresh, green-floral smell, that recalls scent of lily of the valley.[Figure not available: see fulltext.]
A Low Rhodium Content Smart Catalyst for Hydrogenation and Hydroformylation Reactions / Paganelli, S.; Tassini, R.; Rathod, V. D.; Onida, B.; Fiorilli, S.; Piccolo, O.. - In: CATALYSIS LETTERS. - ISSN 1011-372X. - ELETTRONICO. - (2020). [10.1007/s10562-020-03407-5]
| Titolo: | A Low Rhodium Content Smart Catalyst for Hydrogenation and Hydroformylation Reactions | |
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| Data di pubblicazione: | 2020 | |
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| Digital Object Identifier (DOI): | http://dx.doi.org/10.1007/s10562-020-03407-5 | |
| Appare nelle tipologie: | 1.1 Articolo in rivista |
File in questo prodotto:
| File | Descrizione | Tipologia | Licenza | |
|---|---|---|---|---|
| Paganelli2020_Article_ALowRhodiumContentSmartCatalys (1).pdf | 2a Post-print versione editoriale / Version of Record | Non Pubblico - Accesso privato/ristretto | Administrator Richiedi una copia |
http://hdl.handle.net/11583/2851570
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