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EnglishTransition-metal mediated C–H bond activation and functionalization is one of the most straightforward and powerful tools in modern organic synthetic chemistry. Oxidative C–H/C–H coupling reactions between two (hetero)arenes under heterogeneous catalysis may be a valuable means for the production of a plethora of bi(hetero)aryls, and one that adheres to the increasing demand for atom-economic and sustainable chemistry. We have therefore developed a reusable heterogeneous catalytic system, which is based on Pd cross-linked β-cyclodextrin, to perform an efficient microwave-assisted oxidative C–H/C–H cross coupling process between benzothiazoles and methyl thiophene in the presence of green solvents.
Microwave-assisted dehydrogenative cross coupling reactions in γ-valerolactone with a reusable Pd/β-cyclodextrin crosslinked catalyst / Tabasso, S.; Gaudino, E. C.; Acciardo, E.; Manzoli, M.; Giacomino, A.; Cravotto, G.. - In: MOLECULES. - ISSN 1420-3049. - 24:2(2019), pp. 288-301.
| Titolo: | Microwave-assisted dehydrogenative cross coupling reactions in γ-valerolactone with a reusable Pd/β-cyclodextrin crosslinked catalyst |
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| Data di pubblicazione: | 2019 |
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| Digital Object Identifier (DOI): | http://dx.doi.org/10.3390/molecules24020288 |
| Appare nelle tipologie: | 1.1 Articolo in rivista |
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| File | Descrizione | Tipologia | Licenza | |
|---|---|---|---|---|
| molecules-24-00288-v2 (1).pdf | 2a Post-print versione editoriale / Version of Record |  | Visibile a tuttiVisualizza/Apri |
http://hdl.handle.net/11583/2846078
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