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EnglishA rapid Surface Enhanced Raman Spectroscopy (SERS) method to detect SO2 in wine is presented, exploiting the preferential binding of silver nanoparticles (AgNPs) with sulfur-containing species. This interaction promotes the agglomeration of the AgNPs and inducing the formation of SERS “hot spots” responsible for SO2 signals enhancement. For increasing SO2 concentrations from 0 to100 mg/l in wine simulant, SERS intensity showed an increasing trend, following a Langmuir absorption function (R2 = 0.94). Due to the wine matrix variability, a standard additions method was then employed for quantitative analysis in red and white wines. This method does not require the SO2 separation but only a matrix pre-cleaning by solid phase extraction. The limit of detection (LOD) was defined for each wine tested, ranging from 0.6 mg/l to 9.6 mg/l. The results obtained were validated by comparison with the International Organization of Vine and Wine method (OIV-MA-AS323-04A).
Direct quantification of sulfur dioxide in wine by Surface Enhanced Raman Spectroscopy / Mandrile, L.; Cagnasso, I.; Berta, L.; Giovannozzi, A. M.; Petrozziello, M.; Pellegrino, F.; Asproudi, A.; Durbiano, F.; Rossi, A. M.. - In: FOOD CHEMISTRY. - ISSN 0308-8146. - ELETTRONICO. - 326(2020), p. 127009. [10.1016/j.foodchem.2020.127009]
| Titolo: | Direct quantification of sulfur dioxide in wine by Surface Enhanced Raman Spectroscopy | |
| Autori: | ||
| Data di pubblicazione: | 2020 | |
| Rivista: | ||
| Digital Object Identifier (DOI): | http://dx.doi.org/10.1016/j.foodchem.2020.127009 | |
| Appare nelle tipologie: | 1.1 Articolo in rivista |
File in questo prodotto:
| File | Descrizione | Tipologia | Licenza | |
|---|---|---|---|---|
| Revised Manuscript.docx | Articolo principale, senza figure | 2. Post-print / Author's Accepted Manuscript |  | Visibile a tuttiVisualizza/Apri |
| Cagnasso-Direct.pdf | 2a Post-print versione editoriale / Version of Record | Non Pubblico - Accesso privato/ristretto | Administrator Richiedi una copia |
http://hdl.handle.net/11583/2840975
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