In recent years, wide research efforts have been devoted to the development of solid polymer electrolytes (SPEs) with the goal to enhance the intrinsic safety and replace the traditional flammable liquid electrolytes employed in the lithium-ion battery technology. Very commonly, SPEs are composed of a lithium salt dissolved either in a neutral polymer (e.g., PEO) or in an ion-conducting polymer matrix. The latter usually is represented by a new class of polyelectrolytes, namely poly(ionic liquid)s (PILs) [1,2]. Although significant progresses have already been achieved with cationic PILs, the motion of lithium ions carriers in such PIL/Li salt composite separators constitutes only a small fraction (1/5th) of the overall ionic current. This leads to the formation of a strong concentration gradient during battery operation, with deleterious effects such as favored dendritic growth and limited power delivery. Anionic PILs or polymeric single-ion conductors have been recently suggested as an alternative. Differently from other SPEs, a single-ion conductor is composed of a polymeric backbone bearing a covalently bonded anionic moiety and a Li counter-ion free to move and responsible for the ionic conductivity. Given the single-ion nature of the above-mentioned systems, the lithium-ion transport number is noticeably close to the unity. In this work, we present an innovative family of single-ion polymer electrolytes based on specifically developed lithium 1-[3-(methacryloyloxy)propylsulfonyl]-1-(trifluoromethane-sulfonyl)imide ionic monomer. Varying the macromolecular architecture of the polyelectrolytes (i.e., random or block copolymers with poly(ethylene glycol) methyl ether methacrylate or crosslinked networks with poly(ethylene glycol)dimethacrylate) it was possible to develop the SPE with the tailored highest ionic conductivity. A full overview of the electrochemical and thermal properties for the synthesized SPEs will be presented. Finally, the performance of prototype lithium-ion batteries using the best PILs will be shown, which demonstrates their highly promising prospects as next-gen all-solid safe electrolytes.
New polymeric single-ion conductors for rechargeable lithium-battery / Porcarelli, Luca; Shaplov, A. S.; Salsamendi, M.; Bella, Federico; Nair, JIJEESH RAVI; Mecerreyes, D.; Gerbaldi, Claudio. - STAMPA. - (2015), pp. 39-39. (Intervento presentato al convegno XV Sigma-Aldrich Young Chemists Symposium (SAYCS 2015) tenutosi a Rimini (Italy) nel October 27th-29th, 2015).
New polymeric single-ion conductors for rechargeable lithium-battery
PORCARELLI, LUCA;BELLA, FEDERICO;NAIR, JIJEESH RAVI;GERBALDI, CLAUDIO
2015
Abstract
In recent years, wide research efforts have been devoted to the development of solid polymer electrolytes (SPEs) with the goal to enhance the intrinsic safety and replace the traditional flammable liquid electrolytes employed in the lithium-ion battery technology. Very commonly, SPEs are composed of a lithium salt dissolved either in a neutral polymer (e.g., PEO) or in an ion-conducting polymer matrix. The latter usually is represented by a new class of polyelectrolytes, namely poly(ionic liquid)s (PILs) [1,2]. Although significant progresses have already been achieved with cationic PILs, the motion of lithium ions carriers in such PIL/Li salt composite separators constitutes only a small fraction (1/5th) of the overall ionic current. This leads to the formation of a strong concentration gradient during battery operation, with deleterious effects such as favored dendritic growth and limited power delivery. Anionic PILs or polymeric single-ion conductors have been recently suggested as an alternative. Differently from other SPEs, a single-ion conductor is composed of a polymeric backbone bearing a covalently bonded anionic moiety and a Li counter-ion free to move and responsible for the ionic conductivity. Given the single-ion nature of the above-mentioned systems, the lithium-ion transport number is noticeably close to the unity. In this work, we present an innovative family of single-ion polymer electrolytes based on specifically developed lithium 1-[3-(methacryloyloxy)propylsulfonyl]-1-(trifluoromethane-sulfonyl)imide ionic monomer. Varying the macromolecular architecture of the polyelectrolytes (i.e., random or block copolymers with poly(ethylene glycol) methyl ether methacrylate or crosslinked networks with poly(ethylene glycol)dimethacrylate) it was possible to develop the SPE with the tailored highest ionic conductivity. A full overview of the electrochemical and thermal properties for the synthesized SPEs will be presented. Finally, the performance of prototype lithium-ion batteries using the best PILs will be shown, which demonstrates their highly promising prospects as next-gen all-solid safe electrolytes.Pubblicazioni consigliate
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https://hdl.handle.net/11583/2620960
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