In the present paper, we review the consistent definition of macroscopic total energy in classical fluid mechanics, as a function of the microscopic canonical Hamiltonian field, based on a Lennard-Jones model with some spatially varying external field. The macroscopic total energy (sum of mechanical and internal energy) is proved to be equal to the equilibrium ensemble-averaged Hamiltonian. In particular, the conditions for including the effects of the external field both in the macroscopic potential energy and in the internal energy are discussed. {We present the notion of energy as defined in different scientific communities, starting from the standard macroscopic systems all the way down to small ones, which are gaining an increasing popularity.

The notion of energy through multiple scales: From a molecular level to fluid flows and beyond / Asinari, Pietro; Chiavazzo, Eliodoro. - In: ENERGY. - ISSN 0360-5442. - STAMPA. - 68:(2014), pp. 870-876. [10.1016/j.energy.2014.02.016]

The notion of energy through multiple scales: From a molecular level to fluid flows and beyond

ASINARI, PIETRO;CHIAVAZZO, ELIODORO
2014

Abstract

In the present paper, we review the consistent definition of macroscopic total energy in classical fluid mechanics, as a function of the microscopic canonical Hamiltonian field, based on a Lennard-Jones model with some spatially varying external field. The macroscopic total energy (sum of mechanical and internal energy) is proved to be equal to the equilibrium ensemble-averaged Hamiltonian. In particular, the conditions for including the effects of the external field both in the macroscopic potential energy and in the internal energy are discussed. {We present the notion of energy as defined in different scientific communities, starting from the standard macroscopic systems all the way down to small ones, which are gaining an increasing popularity.
2014
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11583/2528287
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