This paper reports a systematic investigation on Mg-substituted hydroxyapatite (Ca10−xMgx(PO4)6(OH)2) nanopowders produced by precipitation of Ca(NO3)2·4H2O and Mg(NO3)2. The Mg content ranged between 0.6 and 2.4 wt%. Semicrystalline Mg-substituted hydroxyapatite powders made up of needle-like nanoparticles were obtained, the specific surface area ranged between 87 and 142m2/g. Pure hydroxyapatite nanopowder decomposed around 1000 ◦C. Mg-substituted hydroxyapatites were thermally stable up to 660 ◦C (x=1.0), 760 ◦C (x=0.5) and 840 ◦C (x=0.25) showing a distinct decreased thermal stability with respect to the pure sample. A relevant displacement of the sintering curve at lower temperature as a function of Mg content was observed, comparing to the behaviour of a pure HAp material, synthesized following the same procedure, and ascribed to the -TCP formation.
Mg-substituted hydroxyapatite nanopowders: Synthesis, thermal stability and sintering behaviour / CACCIOTTI I; BIANCO A; LOMBARDI M; MONTANARO L.. - In: JOURNAL OF THE EUROPEAN CERAMIC SOCIETY. - ISSN 0955-2219. - STAMPA. - 29(2009), pp. 2969-2978. [10.1016/j.jeurceramsoc.2009.04.038]
|Titolo:||Mg-substituted hydroxyapatite nanopowders: Synthesis, thermal stability and sintering behaviour|
|Data di pubblicazione:||2009|
|Digital Object Identifier (DOI):||http://dx.doi.org/10.1016/j.jeurceramsoc.2009.04.038|
|Appare nelle tipologie:||1.1 Articolo in rivista|