The urgent demand for sustainable energy solutions in the face of climate change and resource depletion has catalyzed a global shift toward cleaner energy production and more efficient storage technologies. Lithium-ion batteries (LIBs), as the cornerstone of modern portable electronics, electric vehicles, and grid-scale storage systems, are continually evolving to meet the growing performance requirements. In this dynamic context, two-dimensional (2D) materials have emerged as highly promising candidates for use in electrodes due to their layered structure, tunable electronic properties, and high theoretical capacity. Among 2D materials, molybdenum disulfide (MoS2) has gained increasing attention as a promising low-dimensional candidate for LIB anode applications. This review provides a comprehensive yet concise overview of recent advances in the application of MoS2 in LIB electrodes, with particular attention to its unique electrochemical behavior at the nanoscale. We critically examine the interplay between structural features, charge-storage mechanisms, and performance metrics - chiefly the specific capacity, rate capability, and cycling stability. Furthermore, we discuss current challenges, primarily poor intrinsic conductivity and volume fluctuations, and highlight innovative strategies aimed at overcoming these limitations, such as through nanostructuring, composite formation, and surface engineering. By shedding light on the opportunities and hurdles in this rapidly progressing field, this work offers a forward-looking perspective on the role of MoS2 in the next generation of high-performance LIBs.

A Concise Overview of the Use of Low-Dimensional Molybdenum Disulfide as an Electrode Material for Li-Ion Batteries and Beyond / Bartoli, Mattia; Cinali, Meltem Babayiğit; Coşkun, Özlem Duyar; Porporato, Silvia; Pugliese, Diego; Piatti, Erik; Geobaldo, Francesco; Elia, Giuseppe A.; Gerbaldi, Claudio; Meligrana, Giuseppina; Piovano, Alessandro. - In: BATTERIES. - ISSN 2313-0105. - ELETTRONICO. - 11:7(2025). [10.3390/batteries11070269]

A Concise Overview of the Use of Low-Dimensional Molybdenum Disulfide as an Electrode Material for Li-Ion Batteries and Beyond

Bartoli, Mattia;Porporato, Silvia;Pugliese, Diego;Piatti, Erik;Geobaldo, Francesco;Elia, Giuseppe A.;Gerbaldi, Claudio;Meligrana, Giuseppina;Piovano, Alessandro
2025

Abstract

The urgent demand for sustainable energy solutions in the face of climate change and resource depletion has catalyzed a global shift toward cleaner energy production and more efficient storage technologies. Lithium-ion batteries (LIBs), as the cornerstone of modern portable electronics, electric vehicles, and grid-scale storage systems, are continually evolving to meet the growing performance requirements. In this dynamic context, two-dimensional (2D) materials have emerged as highly promising candidates for use in electrodes due to their layered structure, tunable electronic properties, and high theoretical capacity. Among 2D materials, molybdenum disulfide (MoS2) has gained increasing attention as a promising low-dimensional candidate for LIB anode applications. This review provides a comprehensive yet concise overview of recent advances in the application of MoS2 in LIB electrodes, with particular attention to its unique electrochemical behavior at the nanoscale. We critically examine the interplay between structural features, charge-storage mechanisms, and performance metrics - chiefly the specific capacity, rate capability, and cycling stability. Furthermore, we discuss current challenges, primarily poor intrinsic conductivity and volume fluctuations, and highlight innovative strategies aimed at overcoming these limitations, such as through nanostructuring, composite formation, and surface engineering. By shedding light on the opportunities and hurdles in this rapidly progressing field, this work offers a forward-looking perspective on the role of MoS2 in the next generation of high-performance LIBs.
2025
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11583/3002509