Numerical study of electrode permeability influence on planar SOFC performance

A solid oxide fuel cell (SOFC) is a clean and very efficient electrochemical conversion device, which generates electricity directly from fuel electrochemical oxidation. In this paper, a three dimensional numerical model has been developed in order to analyse the role of some thermophysical and morphological parameters on the performance of the SOFC cell. In particular, we studied the effect of the variation of permeability of the electrodes: fuel distribution, ionic and electric current density, pressure and diffusion flux are analyzed and compared. The volume fraction of the ionic and electronic phase in the electrodes is studied using a parametric study. It was shown that the current density enhanced by decreasing the permeability, up to a defined value, and it diminished with very small permeability. A remarkable influence of pressure and diffusion of species on the performance of the cell, with the variation of permeability, has been recognized. Varying the permeability in the active layer of electrodes has a large impact on the current density, connected to the volume fraction of ionic phase. This study permits to comprehend the relationship between the performance and microstructure of SOFCs. Meanwhile, it furnishes theoretical guidance for an optimum design of the electrode permeability.