Recent experiments report that slowly sheared noncolloidal particle suspensions unexpectedly exhibit rate(omega)-dependent complex viscosities in oscillatory shear, despite a constant relative viscosity in steady shear. Using a minimal hydrodynamic model, we show that van der Waals attraction gives rise to this behavior. At volume fractions phi = 20-50%, the complex viscosities in both experiments and simulations display power-law reductions in shear, with a phi-dependent exponent maximum at phi = 40%, resulting from the interplay between hydrodynamic, collision, and adhesive interactions. Furthermore, this rate dependence is accompanied by diverging particle diffusivities and pronounced cluster formations after repeated oscillations. Previous studies established that suspensions transition from reversible absorbing states to irreversible diffusing states when the oscillation amplitude exceeds a phi-dependent critical value. gamma(c)(0,phi). Here, we show that a second transition to irreversibility occurs below an omega-dependent critical amplitude, gamma(c)(0,omega) <= gamma(c)(0,phi), in the presence of weak attractions.
Irreversibility and rate dependence in sheared adhesive suspensions / Ge, Zhouyang; Martone, Raffaella; Brandt, Luca; Minale, Mario. - In: PHYSICAL REVIEW FLUIDS. - ISSN 2469-990X. - 6:10(2021). [10.1103/physrevfluids.6.l101301]
Irreversibility and rate dependence in sheared adhesive suspensions
Brandt, Luca;
2021
Abstract
Recent experiments report that slowly sheared noncolloidal particle suspensions unexpectedly exhibit rate(omega)-dependent complex viscosities in oscillatory shear, despite a constant relative viscosity in steady shear. Using a minimal hydrodynamic model, we show that van der Waals attraction gives rise to this behavior. At volume fractions phi = 20-50%, the complex viscosities in both experiments and simulations display power-law reductions in shear, with a phi-dependent exponent maximum at phi = 40%, resulting from the interplay between hydrodynamic, collision, and adhesive interactions. Furthermore, this rate dependence is accompanied by diverging particle diffusivities and pronounced cluster formations after repeated oscillations. Previous studies established that suspensions transition from reversible absorbing states to irreversible diffusing states when the oscillation amplitude exceeds a phi-dependent critical value. gamma(c)(0,phi). Here, we show that a second transition to irreversibility occurs below an omega-dependent critical amplitude, gamma(c)(0,omega) <= gamma(c)(0,phi), in the presence of weak attractions.File | Dimensione | Formato | |
---|---|---|---|
PhysRevFluids.6.L101301.pdf
accesso aperto
Tipologia:
2a Post-print versione editoriale / Version of Record
Licenza:
Creative commons
Dimensione
988.16 kB
Formato
Adobe PDF
|
988.16 kB | Adobe PDF | Visualizza/Apri |
Pubblicazioni consigliate
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
https://hdl.handle.net/11583/2990478