The textile wastewater sludge (TWS) treatment and disposal are environmentally challenging due to toxic organics and metals. At the same time, cattle manure (CM), with better combustion performance, i.e., calorific value and uniform burning capability, is still underutilized in many parts of the world. This study evaluated and assessed the TWS and CM blending compatibility to convert them into fuel pellets for the direct combustion option and to stabilize toxic contaminants in TWS. After initial drying, grinding, and particle size control of the raw TWS and CM, both were blended at different ratios. The blended and nonblended TWS and CM samples were converted into pellets and analyzed for proximate and ultimate analyses, namely, moisture content, fixed carbon, CHNO, gross calorific value (GCV), bulk density, ash content, and metals, to evaluate the efficacy for energy applications. Out of three blended ratios, i.e., 75:25 (W/W%; CM/TWS), 50:50, and 25:75, the 75:25 blended pellet composition was found appropriate for fuel application. For the 75:25 blend, the obtained GCV was 12.77 MJ/kg, elemental carbon was 27.5%, volatiles were 41.7%, and residue ash was 42.8% of the total weight. Moreover, the blending ratios of 75:25 and 50:50 revealed that elemental and metal (Fe, Cu, Zn, Ni, Cr, Na, Mg, Mn) concentrations in TWS were stabilized to below threshold limits in the obtained residue ash for safe handling. The explored methods of TWS and CM waste processing, blending, and pelletization proposed a new technique for their sustainable waste valorization into energy sources.

Valorization of Textile Sludge and Cattle Manure Wastes into Fuel Pellets and the Assessment of Their Combustion Characteristics / Gadhi, T. A.; Mahar, R. B.; Qureshi, T. A.; Bawani, M. R.; Khokhar, D. A.; Pinjaro, M. A.; Ansari, I.; Bonelli, B.. - In: ACS OMEGA. - ISSN 2470-1343. - 9:1(2024), pp. 456-463. [10.1021/acsomega.3c05903]

Valorization of Textile Sludge and Cattle Manure Wastes into Fuel Pellets and the Assessment of Their Combustion Characteristics

Gadhi T. A.;Bonelli B.
2024

Abstract

The textile wastewater sludge (TWS) treatment and disposal are environmentally challenging due to toxic organics and metals. At the same time, cattle manure (CM), with better combustion performance, i.e., calorific value and uniform burning capability, is still underutilized in many parts of the world. This study evaluated and assessed the TWS and CM blending compatibility to convert them into fuel pellets for the direct combustion option and to stabilize toxic contaminants in TWS. After initial drying, grinding, and particle size control of the raw TWS and CM, both were blended at different ratios. The blended and nonblended TWS and CM samples were converted into pellets and analyzed for proximate and ultimate analyses, namely, moisture content, fixed carbon, CHNO, gross calorific value (GCV), bulk density, ash content, and metals, to evaluate the efficacy for energy applications. Out of three blended ratios, i.e., 75:25 (W/W%; CM/TWS), 50:50, and 25:75, the 75:25 blended pellet composition was found appropriate for fuel application. For the 75:25 blend, the obtained GCV was 12.77 MJ/kg, elemental carbon was 27.5%, volatiles were 41.7%, and residue ash was 42.8% of the total weight. Moreover, the blending ratios of 75:25 and 50:50 revealed that elemental and metal (Fe, Cu, Zn, Ni, Cr, Na, Mg, Mn) concentrations in TWS were stabilized to below threshold limits in the obtained residue ash for safe handling. The explored methods of TWS and CM waste processing, blending, and pelletization proposed a new technique for their sustainable waste valorization into energy sources.
2024
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11583/2989056