In this work, diopside powder was synthesized through the sol–gel method aiming at obtaining single-phase fine particles. Tetraethyl orthosilicate, calcium nitrate tetrahydrate and magnesium chloride hexahydrate were used as sources of cations, in ratios specific to diopside. Wet gel was synthesized by hydrolyzing a homogeneous solution consisting of precursors dissolved in ethanol. Ground gel powder was investigated by differential thermal analysis and thermogravimetry (DTA-TGA) to define details of the subsequent heat treatments. Samples calcined at 600, 650, 700, 800 and 1100 °C for 3 h underwent characterization through Fourier-transform infrared spectroscopy, X-ray diffraction analysis and scanning electron microscopy. Diopside was found as the single crystalline phase in the interval 600–1100 °C.
Production and characterization of single-phase diopside sol–gel powder / Khamidov, A.; Ruzimuradov, O.; Batirov, D.; Tulyaganov, D. U.; Miola, M.; Baino, F.. - In: MATERIALS LETTERS. - ISSN 0167-577X. - 355:(2024). [10.1016/j.matlet.2023.135570]
Production and characterization of single-phase diopside sol–gel powder
Batirov D.;Miola M.;Baino F.
2024
Abstract
In this work, diopside powder was synthesized through the sol–gel method aiming at obtaining single-phase fine particles. Tetraethyl orthosilicate, calcium nitrate tetrahydrate and magnesium chloride hexahydrate were used as sources of cations, in ratios specific to diopside. Wet gel was synthesized by hydrolyzing a homogeneous solution consisting of precursors dissolved in ethanol. Ground gel powder was investigated by differential thermal analysis and thermogravimetry (DTA-TGA) to define details of the subsequent heat treatments. Samples calcined at 600, 650, 700, 800 and 1100 °C for 3 h underwent characterization through Fourier-transform infrared spectroscopy, X-ray diffraction analysis and scanning electron microscopy. Diopside was found as the single crystalline phase in the interval 600–1100 °C.File | Dimensione | Formato | |
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Diopside sol-gel_Mater Lett 2024.pdf
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Sol-gel diopside powder_R1_final.pdf
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https://hdl.handle.net/11583/2987962