Probability Turns Material: The Boltzmann Equation

We review, under a modern light, the conditions that render the Boltzmann equation applicable. These are conditions that permit probability to behave like mass, thereby possessing clear and concrete content, whereas generally, this is not the case. Because science and technology are increasingly interested in small systems that violate the conditions of the Boltzmann equation, probability appears to be the only mathematical tool suitable for treating them. Therefore, Boltzmann's teachings remain relevant, and the present analysis provides a critical perspective useful for accurately interpreting the results of current applications of statistical mechanics.