Sol-gel Chemistry Approaches for the Manufacturing of Innovative Functional Composites for the Aerospace Sector

Sol-Gel is a "bottom-up" synthesis method that enables the production of films, nano/microparticles, fibers, gels, and bulk materials, both glassy and crystalline. Sol-Gel chemistry can be a vital tool for solving problems in several industrial applications where nanotechnology is necessary to overcome constraints. Here, various examples involving silicate-based materials are discussed. Silicatic materials with a variety of morphologies and applications, e.g., monodisperse SiO2 particles ranging in size from a few nanometers to a micron, can be synthesized through hydrolysis and polycondensation reactions of silicon alkoxide precursors. Using an environmentally friendly electrospinning process, silica nanoparticles can be incorporated into polyvinylpyrrolidone (PVP) fibers to create novel, fire-resistant sound absorbers. Additionally, by employing hybrid techniques based on Sol-Gel, the flame retardance of nanocomposites made of silica and epoxy resin as well as epoxy-based composites including hemp, even cured with cycloaliphatic hardeners, can be enhanced. The development of novel materials beneficial for aviation applications, such as hydrophobic (potentially self-anti-icing) coatings, is a further proof of the effectiveness of Sol-Gel chemistry.