Archivio Istituzionale della RicercaAccording to NMR evidence the metal-mediated sandwich assemblies of porphyrins 2 and 3 undergo in solution a thermally driven motion that resembles that of a stepper: the spontaneous rotational motion of the pyridyl rings is converted into a reciprocating linear motion of the porphyrins. © 2011 The Royal Society of Chemistry.
Concerted motions in supramolecular systems: Metal-mediated assemblies of porphyrins that behave like nanometric step-machines / Iengo, E.; Gatti, T.; Zangrando, E.; Indelli, M. T.; Scandola, F.; Alessio, E.. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - 47:5(2011), pp. 1616-1618. [10.1039/c0cc03513k]
Concerted motions in supramolecular systems: Metal-mediated assemblies of porphyrins that behave like nanometric step-machines
Gatti T.;Alessio E.
2011
Abstract
According to NMR evidence the metal-mediated sandwich assemblies of porphyrins 2 and 3 undergo in solution a thermally driven motion that resembles that of a stepper: the spontaneous rotational motion of the pyridyl rings is converted into a reciprocating linear motion of the porphyrins. © 2011 The Royal Society of Chemistry.
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https://hdl.handle.net/11583/2977491