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EnglishNanocomposites from native cellulose with low 2D nanoplatelet content are of interest as sustainable materials combining functional and structural performance. Cellulose nanofibril-graphene oxide (CNF-GO) nanocomposite films are prepared by a physical mixing-drying method, with a focus on low GO content, the use of very large GO platelets (2-45 μm) and nanostructural characterization using synchrotron X-ray source for WAXS and SAXS. These nanocomposites can be used as transparent coatings, strong films or membranes, as gas barriers or in laminated form. CNF nanofibrils with random in-plane orientation, form a continuous non-porous matrix with GO platelets oriented in-plane. GO reinforcement mechanisms in CNF are investigated, and relationships between nanostructure and suspension rheology, mechanical properties, optical transmittance and oxygen barrier properties are investigated as a function of GO content. A much higher modulus reinforcement efficiency is observed than in previous polymer-GO studies. The absolute values for modulus and ultimate strength are as high as 17 GPa and 250 MPa at a GO content as small as 0.07 vol%. The remarkable reinforcement efficiency is due to improved organization of the CNF matrix; and this GO-induced mechanism is of general interest for nanostructural tailoring of CNF-2D nanoplatelet composites.
Strong reinforcement effects in 2D cellulose nanofibril-graphene oxide (CNF-GO) nanocomposites due to GO-induced CNF ordering / Mianehrow, H.; Lo Re, G.; Carosio, F.; Fina, A.; Larsson, P. T.; Chen, P.; Berglund, L. A.. - In: JOURNAL OF MATERIALS CHEMISTRY. A. - ISSN 2050-7488. - ELETTRONICO. - 8:34(2020), pp. 17608-17620. [10.1039/d0ta04406g]
| Titolo: | Strong reinforcement effects in 2D cellulose nanofibril-graphene oxide (CNF-GO) nanocomposites due to GO-induced CNF ordering | |
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| Data di pubblicazione: | 2020 | |
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| Digital Object Identifier (DOI): | http://dx.doi.org/10.1039/d0ta04406g | |
| Appare nelle tipologie: | 1.1 Articolo in rivista |
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|---|---|---|---|---|
| d0ta04406g.pdf | 2a Post-print versione editoriale / Version of Record |  | Visibile a tuttiVisualizza/Apri |
http://hdl.handle.net/11583/2851840
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