Monolayer black and blue phosphorenes possess electronic and optical properties that result in unique features when the two materials are stacked. We devise a low-strain van-der-Waals double layer and investigate its properties with ab initio many-body perturbation theory techniques. A type-II band alignment and optical absorption in the visible range are found. The study demonstrates that spatially indirect excitons with full charge separation can be obtained between two layers with the same elemental composition but different crystalline structure, proving the system interesting for further studies where dipolar excitons are important and for future optoelectronic applications.
Spatially indirect excitons in black and blue phosphorene double layers / RE FIORENTIN, Michele; Cicero, Giancarlo; Palummo, Maurizia. - In: PHYSICAL REVIEW MATERIALS. - ISSN 2475-9953. - ELETTRONICO. - 4:7(2020), p. 074009. [10.1103/PhysRevMaterials.4.074009]
Spatially indirect excitons in black and blue phosphorene double layers
Michele Re Fiorentin;Giancarlo Cicero;
2020
Abstract
Monolayer black and blue phosphorenes possess electronic and optical properties that result in unique features when the two materials are stacked. We devise a low-strain van-der-Waals double layer and investigate its properties with ab initio many-body perturbation theory techniques. A type-II band alignment and optical absorption in the visible range are found. The study demonstrates that spatially indirect excitons with full charge separation can be obtained between two layers with the same elemental composition but different crystalline structure, proving the system interesting for further studies where dipolar excitons are important and for future optoelectronic applications.File | Dimensione | Formato | |
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https://hdl.handle.net/11583/2851520