Preparation and characterization of UV-LED curable acrylic films containing biochar and/or multiwalled carbon nanotubes: effect of the filler loading on the rheological, thermal and optical properties.

UV-LED curable coatings represent an up-to-date attractive field due to the high curing eciency even in the presence of high filler loadings, as well as to the absence of infrared wavelengths that may negatively impact on heat-sensitive substrates. The addition of carbonaceous materials, such as biochar (BC) and/or multiwalled carbon nanotubes (MWCNTs) could positively improve both the rheological and thermal properties. In this study we report on the synthesis and characterization of carbon-reinforced films containing nanometric (MWCNTs) and micrometric (BC) carbon-based materials. We analyze the rheological properties of the UV-LED curable dispersions, as well as the thermal and optical properties of the resulting films, establishing some correlations between filler dispersion/loading with the main observed properties.