Critical issues in the determination of the bentonite cation exchange capacity

The swelling pressure and transport properties of bentonites are controlled by the electric charge density of solid particles, which is commonly estimated from the laboratory measurement of the cation exchange capacity (CEC). However, the standard ammonium displacement method for CEC determination does not take into account the fabric changes that occur in bentonites under exposure to high salt concentration solutions. A series of laboratory tests was conducted to assess the relevance of such a critical issue, by varying the concentration of the extracting KCl solution with respect to that of the standard test. The obtained results show that the release of the adsorbed ammonium cations depends on the bentonite fabric, which is controlled by the KCl concentration. As a consequence, the ammonium displacement method may provide an unrepresentative estimate of the CEC of bentonites. The methylene blue titration method, despite its apparently more limited accuracy, instead seems to provide a more reliable estimation of the CEC, as the bentonite fabric is maintained dispersed during the test.