Power-to-X and power-to-power routes

The increasing dependence on a worldwide scale of the power generation sector on non-dispatchable renewable sources, such as wind or solar, is posing challenges to the electricity infrastructures that require flexibility solutions to keep the balance between power supply and demand. Flexible generation, energy storage, demand side response are among the several strategies pursued to increase the flexibility of electricity management in the presence of a large share of RES generation, but flexibility can also derive by the conversion of electricity to other energy commodities. Among the secondary energy carriers, electricity can be stored in the form of chemical potential following the so-called “Power-to-X” scheme. In this route, electricity is converted in energy carriers, such as hydrogen, that can be exploited not only for time-shifted power delivery (“X-to-Power” reverse scheme), but also employed to cover nonelectrical demand in different sectors, such as transportation, heating, and industry. This chapter provides a detailed description of the different routes in the Power-to-X scheme, highlighting the technologies, the benefits and services provided to the energy system, the strengths and criticality points, the possible applications of the output streams, and the lessons learned from projects and demonstrations worldwide.