Archivio Istituzionale della RicercaOuter Co(II) species in Co-ZIF-67 coordinate molecular oxygen both from the gas phase and liquid water, through an adsorption process (presumably yielding in both cases surface superoxo species), respectively weak and reversible (gas phase), and strong and irreversible (liquid); in the latter case desorption is however brought about by illumination with solar light comprising the UV component.
Outer Co(ii) ions in Co-ZIF-67 reversibly adsorb oxygen from both gas phase and liquid water / Saracco, Guido; VANKOVA KRASIMIROVA, Svetoslava; Pagliano, Cristina; Bonelli, Barbara; Garrone, Edoardo. - In: PHYSICAL CHEMISTRY CHEMICAL PHYSICS. - ISSN 1463-9076. - STAMPA. - 16:(2014), pp. 6139-6145. [10.1039/c3cp54896a]
Outer Co(ii) ions in Co-ZIF-67 reversibly adsorb oxygen from both gas phase and liquid water
SARACCO, GUIDO;VANKOVA KRASIMIROVA, SVETOSLAVA;PAGLIANO, CRISTINA;BONELLI, Barbara;GARRONE, EDOARDO
2014
Abstract
Outer Co(II) species in Co-ZIF-67 coordinate molecular oxygen both from the gas phase and liquid water, through an adsorption process (presumably yielding in both cases surface superoxo species), respectively weak and reversible (gas phase), and strong and irreversible (liquid); in the latter case desorption is however brought about by illumination with solar light comprising the UV component.
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https://hdl.handle.net/11583/2555937
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