A kinetic model for self-sustained isothermal oscillations occurring during N2O decomposition on Cu-ZSM5 has been developed. The dynamic behaviour has been explained by a reaction mechanism producing periodic changes of the state of oxidation of the catalyst. The oscillations have been simulated by assuming that the solid-solid reaction step exhibits an activation energy proportional to the catalyst reduction degree
MATHEMATICAL MODELLING OF SELF-SUSTAINED ISOTHERMAL OSCILLATIONS IN N2O DECOMPOSITION ON Cu-ZSM5 / P. Ciambelli; A. Di Benedetto; R. Pirone; G. Russo. - In: CHEMICAL ENGINEERING SCIENCE. - ISSN 0009-2509. - STAMPA. - 54:13-14(1999), pp. 2555-2559. [10.1016/S0009-2509(98)00469-2]
Titolo: | MATHEMATICAL MODELLING OF SELF-SUSTAINED ISOTHERMAL OSCILLATIONS IN N2O DECOMPOSITION ON Cu-ZSM5 | |
Autori: | ||
Data di pubblicazione: | 1999 | |
Rivista: | ||
Digital Object Identifier (DOI): | http://dx.doi.org/10.1016/S0009-2509(98)00469-2 | |
Appare nelle tipologie: | 1.1 Articolo in rivista |
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