The influence of heat treatments on the corrosion resistance of some base-metal alloys currently used in dentistry as a base for porcelain substrate systems has been investigated. Four Co-Cr alloys (Wironit, Wironit extra hard, Wirobond and Wirolloy) and two Ni-Cr alloys (Wiron 88 and Wirolloy) were submitted to heat treatments for 30 min at 880, 980, 1080 °C for 30 min, and slowly cooled in air. The electrochemical characterization was performed by means of anodic polarization curves in Ringer's solution and artificial saliva at 37 °C. In both solutions it was found that ageing at 880 °C detrimentally affects the corrosion resistance of Co-Cr alloys; the passive zone is narrow and shows rather high current densities. On the contrary, the samples annealed at 1080 °C display a superior corrosion resistance. With Wiron 88 the effect is opposite, but the electrochemical behaviour of Wirolloy, is not affected by heat treatments; although it does have a more negative transpassive potential in artificial saliva and cannot be passivated in Ringer's solution. The SEM examination of the alloys evinces the microstructural modifications induced by heat treatments responsible for changes in the corrosion behaviour of the base-metal alloys.

In vitro corrosion of some Co-Cr and Ni-Cr alloys used for removable partial dentures: influence of heat treatments / Angelini, EMMA PAOLA MARIA VIRGINIA; F., Zucchi. - In: JOURNAL OF MATERIALS SCIENCE. MATERIALS IN MEDICINE. - ISSN 0957-4530. - STAMPA. - 2:1(1991), pp. 27-35. [10.1007/BF00701684]

In vitro corrosion of some Co-Cr and Ni-Cr alloys used for removable partial dentures: influence of heat treatments

ANGELINI, EMMA PAOLA MARIA VIRGINIA;
1991

Abstract

The influence of heat treatments on the corrosion resistance of some base-metal alloys currently used in dentistry as a base for porcelain substrate systems has been investigated. Four Co-Cr alloys (Wironit, Wironit extra hard, Wirobond and Wirolloy) and two Ni-Cr alloys (Wiron 88 and Wirolloy) were submitted to heat treatments for 30 min at 880, 980, 1080 °C for 30 min, and slowly cooled in air. The electrochemical characterization was performed by means of anodic polarization curves in Ringer's solution and artificial saliva at 37 °C. In both solutions it was found that ageing at 880 °C detrimentally affects the corrosion resistance of Co-Cr alloys; the passive zone is narrow and shows rather high current densities. On the contrary, the samples annealed at 1080 °C display a superior corrosion resistance. With Wiron 88 the effect is opposite, but the electrochemical behaviour of Wirolloy, is not affected by heat treatments; although it does have a more negative transpassive potential in artificial saliva and cannot be passivated in Ringer's solution. The SEM examination of the alloys evinces the microstructural modifications induced by heat treatments responsible for changes in the corrosion behaviour of the base-metal alloys.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11583/1653869
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