Archivio Istituzionale della RicercaThe main characteristics of the evolution of HCl and SbCl3 during the thermal degradation of chloroparaffin-Sb2O3 mixtures, which are typical fire retardant additives for polymers, have been studied. Sb2O3 reacts with HCl evolved from the chloroparaffin without any apparent effect on the dehydrochlorination process itself. Evolution of SbCl3 occurs at a maximum rate between 300 and 350°C and is somewhat delayed in the earlier stage of reaction, depending on the composition of the mixture.
Thermal degradation of fire retardant chloroparaffin - metal compound mixtures. Part I: Antimony oxide / Costa, L.; Camino, Giovanni; Trossarelli, L.. - In: POLYMER DEGRADATION AND STABILITY. - ISSN 0141-3910. - 5:4(1983), pp. 267-273. [10.1016/0141-3910(83)90018-6]
Thermal degradation of fire retardant chloroparaffin - metal compound mixtures. Part I: Antimony oxide
CAMINO, GIOVANNI;
1983
Abstract
The main characteristics of the evolution of HCl and SbCl3 during the thermal degradation of chloroparaffin-Sb2O3 mixtures, which are typical fire retardant additives for polymers, have been studied. Sb2O3 reacts with HCl evolved from the chloroparaffin without any apparent effect on the dehydrochlorination process itself. Evolution of SbCl3 occurs at a maximum rate between 300 and 350°C and is somewhat delayed in the earlier stage of reaction, depending on the composition of the mixture.
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https://hdl.handle.net/11583/1430133
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