Archivio Istituzionale della RicercaWe analyze the influence of the adsorption of ions at the interfaces on the transient phenomena occurring in an electrolytic cell submitted to a steplike external voltage. In the limit of small amplitude of the applied voltage, where the equation of the problem can be linearized, we obtain an analytical solution for the bulk and surface densities of ions and for the electrical potential. We also obtain, in this limit, the relaxation time for the transient phenomena.
Role of the adsorption phenomenon on the ionic equilibrium distribution and on the transient effects in electrolytic cells / Barbero, Giovanni; Freire, Fcm; Scalerandi, Marco; Alexe Ionescu, Al. - In: JOURNAL OF PHYSICAL CHEMISTRY. B, CONDENSED MATTER, MATERIALS, SURFACES, INTERFACES & BIOPHYSICAL. - ISSN 1520-6106. - 110:(2006), pp. 17889-17897. [10.1021/jp062271n]
Role of the adsorption phenomenon on the ionic equilibrium distribution and on the transient effects in electrolytic cells
BARBERO, GIOVANNI;SCALERANDI, MARCO;
2006
Abstract
We analyze the influence of the adsorption of ions at the interfaces on the transient phenomena occurring in an electrolytic cell submitted to a steplike external voltage. In the limit of small amplitude of the applied voltage, where the equation of the problem can be linearized, we obtain an analytical solution for the bulk and surface densities of ions and for the electrical potential. We also obtain, in this limit, the relaxation time for the transient phenomena.
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https://hdl.handle.net/11583/1405600
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