Chitosan is a biopolymer with unequalled properties such as biodegradability, nontoxicity, and antimicrobial activity. It is a carbohydrate polymer derived from the deacetylation of the chitin component of the shells of crustacean; hence, it is a renewable material widely available as a byproduct of the food industry. Owing to its extremely interesting properties, chitosan has been extensively applied to textile fibers to confer various functional properties such as • antimicrobial activity with a green chemistry approach for aesthetic, hygienic, and medical applications; • antifelting properties for wool fabrics; • increasing uptake of ionic dyes in dyeing processes; • removal of dyes and other organic pollutants from wastewaters; • removal of heavy metal ions from contaminated wastewaters. A fundamental problem that arises in order to obtain durable chitosan coatings on textiles is due to the low wash fastness of the biopolymer; hence, thermal treatments or cross-linking agents are needed to obtain strong bonding with the fibers. Wet thermal curing involves energy consumption and possible fiber degradation, whereas the most of cross-linking agents such as dialdehydes are toxic. Therefore, many research works were aimed to investigate safer grafting methods with physical means such as UV irradiation or with green chemicals.
Chitosan Coating on Textile Fibers for Functional Properties / Ferrero, Franco; Periolatto, Monica - In: Handbook of Composites from Renewable Materials, Volume 4, Functionalization / Thakur V.K., Thakur M.K., Kessler M.R.. - STAMPA. - Austin, Texas, USA : Wiley Scrivener Publishing, 2017. - ISBN 978-1-119-22367-2. - pp. 165-197
Chitosan Coating on Textile Fibers for Functional Properties
FERRERO, Franco;PERIOLATTO, MONICA
2017
Abstract
Chitosan is a biopolymer with unequalled properties such as biodegradability, nontoxicity, and antimicrobial activity. It is a carbohydrate polymer derived from the deacetylation of the chitin component of the shells of crustacean; hence, it is a renewable material widely available as a byproduct of the food industry. Owing to its extremely interesting properties, chitosan has been extensively applied to textile fibers to confer various functional properties such as • antimicrobial activity with a green chemistry approach for aesthetic, hygienic, and medical applications; • antifelting properties for wool fabrics; • increasing uptake of ionic dyes in dyeing processes; • removal of dyes and other organic pollutants from wastewaters; • removal of heavy metal ions from contaminated wastewaters. A fundamental problem that arises in order to obtain durable chitosan coatings on textiles is due to the low wash fastness of the biopolymer; hence, thermal treatments or cross-linking agents are needed to obtain strong bonding with the fibers. Wet thermal curing involves energy consumption and possible fiber degradation, whereas the most of cross-linking agents such as dialdehydes are toxic. Therefore, many research works were aimed to investigate safer grafting methods with physical means such as UV irradiation or with green chemicals.Pubblicazioni consigliate
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https://hdl.handle.net/11583/2669974
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