The development of an electrochemical dissolved oxygen (DO) sensor based on a novel Cu(II) complex-modified screen printed carbon electrode is reported. The voltammetric behavior of the modified electrode was investigated at different scan rates and oxygen concentrations in PBS (pH = 7). An increase of cathodic current (at about -0.4 vs. Ag/AgCl) with the addition of oxygen was observed. The modified Cu(II) complex electrode was demonstrated for the determination of DO in water using chronoamperometry. A small size and low power consumption home-made portable electrochemical analyzer based on custom electronics for sensor interfacing and operating in voltammetry and amperometry modes has been also designed and fabricated. Its performances in the monitoring of DO in water were compared with a commercial one.
Development of a Novel Cu(II) Complex Modified Electrode and a Portable Electrochemical Analyzer for the Determination of Dissolved Oxygen (DO) in Water / Leonardi, Salvatore; Bonyani, Maryam; Ghosh, Kaushik; Dhara, Ashish; Lombardo, Luca; Donato, Nicola; Neri, Giovanni. - In: CHEMOSENSORS. - ISSN 2227-9040. - ELETTRONICO. - 4:2(2016), pp. 1-10. [10.3390/chemosensors4020007]
Development of a Novel Cu(II) Complex Modified Electrode and a Portable Electrochemical Analyzer for the Determination of Dissolved Oxygen (DO) in Water
LOMBARDO, LUCA;
2016
Abstract
The development of an electrochemical dissolved oxygen (DO) sensor based on a novel Cu(II) complex-modified screen printed carbon electrode is reported. The voltammetric behavior of the modified electrode was investigated at different scan rates and oxygen concentrations in PBS (pH = 7). An increase of cathodic current (at about -0.4 vs. Ag/AgCl) with the addition of oxygen was observed. The modified Cu(II) complex electrode was demonstrated for the determination of DO in water using chronoamperometry. A small size and low power consumption home-made portable electrochemical analyzer based on custom electronics for sensor interfacing and operating in voltammetry and amperometry modes has been also designed and fabricated. Its performances in the monitoring of DO in water were compared with a commercial one.File | Dimensione | Formato | |
---|---|---|---|
chemosensors.pdf
accesso aperto
Descrizione: articolo in rivista
Tipologia:
2a Post-print versione editoriale / Version of Record
Licenza:
Creative commons
Dimensione
3.25 MB
Formato
Adobe PDF
|
3.25 MB | Adobe PDF | Visualizza/Apri |
Pubblicazioni consigliate
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
https://hdl.handle.net/11583/2684565